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Chemistry in CALCULA

The Chemistry field covers solutions (concentration, dilution), acids and bases, equilibria, kinetics and thermochemistry.

Concentration and dilution

n = m / M  ·  C = n / V  ·  C₁·V₁ = C₂·V₂

A weighed mass becomes an amount of substance (moles) through the molar mass, then a concentration by dividing by the volume. Diluting conserves the amount of solute: the product concentration × volume stays constant.

Example

To prepare 250 mL of 0.1 mol/L salt solution from a 1 mol/L stock, take 25 mL of stock and make it up to 250 mL.

pH and equilibria

pH = −log₁₀[H₃O⁺]  ·  pH + pOH = 14 (at 25 °C)

pH measures acidity on a logarithmic scale: one pH unit is a factor of 10 on the H₃O⁺ concentration. A solution at pH 3 is ten times more acidic than one at pH 4.

Kinetics and thermochemistry

k = A·e^(−Eₐ/RT)  ·  ΔG = ΔH − T·ΔS

The Arrhenius law links a reaction's rate to temperature and activation energy: raising the temperature speeds it up sharply. The sign of the Gibbs free energy ΔG tells whether a transformation is spontaneous (ΔG < 0).

Example

A reaction whose rate doubles every 10 °C (a rule of thumb) is about 8 times faster at 60 °C than at 30 °C.

Typing it into CALCULA

Choose the sub-field in the “≡” menu, then fill in molar mass, volume, concentration or temperature depending on the calculation. Radiometric dating has its own guide.